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In-situ Observation of Crack Initiation and Propagation in the NCM811 Cathode particles
Mälardalens universitet, Akademin för ekonomi, samhälle och teknik, Framtidens energi. Key Laboratory of Advanced Battery Systems and Safety (CPCIF), School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai, China.
Key Laboratory of Advanced Battery Systems and Safety (CPCIF), School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai, China.
Key Laboratory of Advanced Battery Systems and Safety (CPCIF), School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai, China.
Mälardalens universitet, Akademin för ekonomi, samhälle och teknik, Framtidens energi.ORCID-id: 0000-0002-6279-4446
2024 (engelsk)Inngår i: Energy Proceedings, Scanditale AB , 2024, Vol. 43Konferansepaper, Publicerat paper (Fagfellevurdert)
Abstract [en]

Layered nickel-rich oxide LiNixCoyMn1-x-yO2 (0.6 ≤x<1) is a highly promising positive electrode material. However, the cycling stability of nickel-rich positive electrode materials is limited by particle fracture and a series of side reactions. A comprehensive understanding of particle cracking mechanisms is paramount for material optimization, but crack initiation and propagation have received limited research attention. This paper uses a quasi in-situ SEM observation method and an in-situ optical microscopy observation method to observe crack evolution in real time. The results show rapid cracking behavior under hazardous operating conditions and cracking during cycling under mild conditions. Center cracks and surface cracks are observed during cycling. The observation methods and these insights into the crack behavior offer theoretical guidance for the structural engineering of NCM cathode particles.

sted, utgiver, år, opplag, sider
Scanditale AB , 2024. Vol. 43
Serie
Energy Proceedings, ISSN 20042965
Emneord [en]
crack, in-situ optical microscopy, NCM cathode particle, prolonged cycling, quasi in-situ SEM
HSV kategori
Identifikatorer
URN: urn:nbn:se:mdh:diva-66567DOI: 10.46855/energy-proceedings-11046Scopus ID: 2-s2.0-85190886732OAI: oai:DiVA.org:mdh-66567DiVA, id: diva2:1857638
Konferanse
15th International Conference on Applied Energy, ICAE 2023. Doha. 3 December 2023 through 7 December 2023
Tilgjengelig fra: 2024-05-14 Laget: 2024-05-14 Sist oppdatert: 2025-10-10bibliografisk kontrollert

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