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One-Pot Catalytic Conversion of Raw Lignocellulosic Biomass into Gasoline Alkanes and Chemicals over LiTaMoO6 and Ru/C in Aqueous Phosphoric Acid
Chinese Academy of Sciences, Guangzhou, China.
Chinese Academy of Sciences, Guangzhou, China.
Chinese Academy of Sciences, Guangzhou, China.
Chinese Academy of Sciences, Guangzhou, China.
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2015 (English)In: ACS Sustainable Chemistry and Engineering, ISSN 2168-0485, Vol. 3, no 8, p. 1745-1755Article in journal (Refereed) Published
Abstract [en]

Lignocellulosic biomass is a renewable feedstock that has the potential to replace the diminishing fossil fuels. Herein, we reported the simultaneous conversion of cellulose, hemicellulose and lignin from raw biomass into gasoline alkanes (hexanes and pentanes) and monophenols and related hydrocarbons over layered LiTaMoO<inf>6</inf> and Ru/C in aqueous phosphoric acid medium. Specifically, gasoline alkanes were directly yielded from the carbohydrate components, based on hemicellulose and cellulose, and the total yield could be up to 82.4%. Notably, the lignin fraction could also be transformed into monophenols, related alcohols and hydrocarbons by the one-pot reaction. It suggested that the hydrocracking of monophenol fraction could be performed in this catalytic system. The total yield of volatile products was 53% based on the lignin fraction. In this paper, the influences of phosphoric acid concentration, substrate ash and the amino acids derived from the biogenic impurities were investigated and different raw biomass substrates were tested. Furthermore, the catalysts could be reused for several runs to convert raw biomass without pretreatment.

Place, publisher, year, edition, pages
2015. Vol. 3, no 8, p. 1745-1755
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:mdh:diva-28714DOI: 10.1021/acssuschemeng.5b00256ISI: 000359098400010Scopus ID: 2-s2.0-84938560202OAI: oai:DiVA.org:mdh-28714DiVA, id: diva2:847886
Available from: 2015-08-21 Created: 2015-08-21 Last updated: 2016-12-28Bibliographically approved

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CiteExportLink to record
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