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Synthesis and Crystal Structure of the Palladium(IV) Polyoxomolybdate, K0 75Na3 75[PdMo6O24H3 5]center dot 17H(2)O
Mälardalen University, Department of Biology and Chemical Engineering.
2010 (English)In: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 636, no 5, 727-734 p.Article in journal (Refereed) Published
Abstract [en]

The first example of a heteropolyoxomolybdate containing palladium(IV) was isolated and characterized by X ray crystallography The palladium(IV) hexamolybdate, K0 75Na3 75[PdMo6O24H3 (5)] 17H(2)O, was isolated from an aqueous solution at pH 4 5 in the space group P (1) over bar a 10 790(2) b 12 244(3), c 14 086(3) angstrom, alpha 113 77(1), beta 90 41(1) gamma 107 86(1)degrees and the structure was determined using X ray diffraction methods refining to a residual of 0 0301 for 5334 reflections A formal [PdMo6O24H3](5-) subunit exhibits the basic Anderson structure with two [PdMo6O24H3](5-) cluster anions in the structure bridged by a hydrogen atom (formally an H+) situated on a center of symmetry to give a [Pd2Mo12O48H7](9-) dimeric anion The palladium(IV) atom occupies a slightly distorted octahedral environment with Pd-O distances ranging from 1 968 to 2 009 angstrom.

Place, publisher, year, edition, pages
2010. Vol. 636, no 5, 727-734 p.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:mdh:diva-20237DOI: 10.1002/zaac.200900129ISI: 000277298400009Scopus ID: 2-s2.0-77950827652OAI: oai:DiVA.org:mdh-20237DiVA: diva2:635826
Available from: 2013-07-05 Created: 2013-07-05 Last updated: 2013-07-05Bibliographically approved

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