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Primary and digested sludge-derived char as a Cd sorbent: feasibility of local utilisation
Mälardalen University, School of Business, Society and Engineering, Future Energy Center.ORCID iD: 0000-0002-9373-2774
Univ Oulu, Res Unit Sustainable Chem, POB 8000, FI-90014 Oulu, Finland..ORCID iD: 0000-0001-9479-3563
Univ Oulu, Res Unit Sustainable Chem, POB 8000, FI-90014 Oulu, Finland..
Mälardalen University, School of Business, Society and Engineering, Future Energy Center.ORCID iD: 0000-0003-0231-564X
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2023 (English)In: Water Science and Technology, ISSN 0273-1223, E-ISSN 1996-9732, Vol. 11, p. 2917-2930Article in journal (Refereed) Published
Abstract [en]

Cadmium (Cd) is a highly toxic metal, occurring in municipal wastewater and stormwater as well as in wastewater from various industries. Char derived from the pyrolysis of municipal sewage sludge has the potential to be a low-cost sorption media for the removal of Cd. However, the balance between possible local char production and demand has not been assessed previously. In this study, the Cd sorption capacities of chars derived from primary (PSC) and secondary sludge (DSC), as well as the feasibility of char production for Cd sorbent purposes, and the pyrolysis energy balance were evaluated. Results showed that the sorption capacity of PSC (9.1 mg/g; 800 degrees C, 70 min) was superior to that of DSC (6.0 mg/g; 800 degrees C, 70 min), and increased with a higher pyrolysis temperature. Pyrolysis of primary sludge had a more favourable energy balance compared with the pyrolysis of digested sludge, however, when accounting for loss of biogas production the energy balance of primary sludge pyrolysis was negative. Assessment of the regional demand (V & auml;ster & aring;s, Sweden) indicated that PSC or DSC may cover the local Cd sorbent demand. However, it was estimated that large char volumes would be required, thus making the use of DSC/PSC less feasible.

Place, publisher, year, edition, pages
IWA PUBLISHING , 2023. Vol. 11, p. 2917-2930
Keywords [en]
adsorbent, adsorption, biochar, biosolids, biosorbent, WRRF
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:mdh:diva-65130DOI: 10.2166/wst.2023.356ISI: 001103107800001PubMedID: 38096078Scopus ID: 2-s2.0-85179766907OAI: oai:DiVA.org:mdh-65130DiVA, id: diva2:1821382
Available from: 2023-12-20 Created: 2023-12-20 Last updated: 2024-01-03Bibliographically approved

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Sylwan, IdaWestholm, Lena JohanssonThorin, Eva

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