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PVTxy Properties of CO2 Mixtures for CCS: An Update of Experimental Data and Models Since 2009
Tianjin Univ Commerce, Key Lab Refrigerat Technol Tianjin, Peoples R China.
Mälardalen University, School of Business, Society and Engineering, Future Energy Center. Tianjin Univ Commerce, Key Lab Refrigerat Technol Tianjin, Peoples R China.ORCID iD: 0000-0002-6279-4446
Tianjin Univ Commerce, Key Lab Refrigerat Technol Tianjin, Peoples R China.
2018 (English)In: JOINT INTERNATIONAL CONFERENCE ON ENERGY, ECOLOGY AND ENVIRONMENT ICEEE 2018 AND ELECTRIC AND INTELLIGENT VEHICLES ICEIV 2018, DESTECH PUBLICATIONS, INC , 2018Conference paper, Published paper (Refereed)
Abstract [en]

The latest progress on the experimental data and theoretical models regarding PVTxy properties of CO2 mixtures has been updated. This review shows that more experimental data are available, such as the vapor liquid equilibrium (VLE) of CO2/NO and the density of CO2/O-2. But there are still some clear deficiencies: for example, there have been no data on VLE of CO2/COS and density of CO2/NH3; there are only few points on VLE of CO2/NH3 and CO2/N2O, and density of binary mixtures containing CO, N2O4, COS and H2S. Several new models exhibit advantages for calculating PVTxy properties of CO2 mixtures. For example, Equation of State for Combustion Gases and Combustion Gas-like Mixtures (EOS-CG) shows better accuracy on both phase equilibrium and density than GERG-2008 except for the critical region. Peng-Robinson+ residual Helmholtz energy-based model (PR + EOS/(E,Wilson)(ares)) displays significant improvement in the representation of high-pressure critical region (deviation decreasing from 12.6% to 1% for CO2/O-2/N-2) and wider application of polar and non-polar mixtures for VLE.

Place, publisher, year, edition, pages
DESTECH PUBLICATIONS, INC , 2018.
Series
DEStech Transactions on Environment Energy and Earth Sciences, ISSN 2475-8833
Keywords [en]
thermodynamic properties, vapor liquid equilibrium, density, experimental data, modeling
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:mdh:diva-43984ISI: 000468631900130ISBN: 978-1-60595-590-2 (print)OAI: oai:DiVA.org:mdh-43984DiVA, id: diva2:1323666
Conference
International Conference on Energy, Ecology and Environment (ICEEE) / International Conference on Electric and Intelligent Vehicles (ICEIV), NOV 21-25, 2018, Swinburne Univ Technol, Melbourne, AUSTRALIA
Available from: 2019-06-12 Created: 2019-06-12 Last updated: 2019-06-12Bibliographically approved

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