This study presented an experimental investigation on solidification behavior of fluid saturated in highly porous open-cell copper foams. Particular attention has been made on the effect of pore parameters (pore density and porosity) on the solidification behavior. A purposely-designed apparatus was built for experimental observations. Results showed that the copper foam had a great effect on solidification and the full solidification time can be saved up to 50%, especially preventing the decrease in solidification rate during the later stage of phase change. The smaller the porosity is, the faster the solidification rate will be. Pore density was found to have little influence upon the solidification rate. In addition, the local natural convection does exist but it has a slight effect on solidification, leading to the slant of the solid-liquid interface.