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Mobilized Thermal Energy Storage for Heat Recovery for Distributed Heating
Mälardalens högskola, Akademin för hållbar samhälls- och teknikutveckling. (Bioenergy)
2010 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

Conventional energy sources—oil and electricity—dominate the heat supply market. Due to their rising costs and their negative environmental effects on global climate change, it is necessary to develop an alternative heat supply system featuring low cost, high energy efficiency and environment friendliness. At present, it is often challenging to supply heat to detached buildings due to low energy efficiency and high distribution cost. Meanwhile, significant amounts of industrial waste and excess heat are released into the environment without recycling due to the difficulty of matching time and space differences between suppliers and end users. Phase change materials (PCMs), with the advantages of being storable and transportable, offer a solution for delivering that excess heat from industrial plants to detached buildings in sparse, rural areas.

 

The objective of this thesis is to study PCMs and latent thermal energy storage (LTES) technology, and to develop a mobilized thermal energy storage (M-TES) system that can use industrial waste or excess heat for heat recovery and distribution to areas in need.

 

Organic PCMs were chosen for study because they are non-toxic and non-corrosive, and they exhibit no phase separation and little sub-cooling when compared to inorganic PCMs. Two major issues including leakage of liquid PCMs and low thermal conductivity. Polyethylene glycol (PEG) was chosen to help analyze the thermal behavior of organic PCMs and PEG-based form-stable composites. To overcome the issue of low thermal conductivity, modified aluminum nitride (AlN) powder was added to the composites. Increased thermal conductivity traded off decreased latent heat. The PEG/EG composite, prepared by mixing the melted PEG into an expanded graphite (EG) matrix showed good thermal performance due to its large enthalpy and high thermal conductivity.

 

To make a systematic study of the M-TES system, a compact lab-scale system was designed and built. Characteristics of PCM were studied, and the performance of the direct-contact TES container was investigated. A case study using an M-TES system to deliver heat from a combined heat and power (CHP) plant to a small village was conducted. A technical and economic feasibility study was conducted for an integrated heat supply system using the M-TES system. In addition, the options for charging a TES container at a CHP plant were analyzed and compared from the viewpoints of power output, heat output and incomes.

sted, utgiver, år, opplag, sider
Västerås: Mälardalen University , 2010.
Serie
Mälardalen University Press Dissertations, ISSN 1651-4238 ; 92
HSV kategori
Forskningsprogram
energi- och miljöteknik
Identifikatorer
URN: urn:nbn:se:mdh:diva-11142ISBN: 978-91-86135-98-0 (tryckt)OAI: oai:DiVA.org:mdh-11142DiVA, id: diva2:371257
Disputas
2010-12-20, Lambda, Mälardalen University, Västerås, 10:00 (engelsk)
Opponent
Veileder
Prosjekter
Ångpanneföreningens Forskningsstiftelse (ÅF)Tilgjengelig fra: 2010-11-22 Laget: 2010-11-18 Sist oppdatert: 2010-11-29bibliografisk kontrollert
Delarbeid
1. Preparation and performance of form-stable polyethylene glycol/silicon dioxide composites as solid–liquid phase change materials
Åpne denne publikasjonen i ny fane eller vindu >>Preparation and performance of form-stable polyethylene glycol/silicon dioxide composites as solid–liquid phase change materials
2009 (engelsk)Inngår i: Applied Energy, ISSN 0306-2619, E-ISSN 1872-9118, Vol. 86, nr 2, s. 170-174Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

This work mainly involved the preparation and characterization of form-stable polyethylene glycol (PEG)/silicon dioxide (SiO2) composite as a novel solid–liquid phase change material (PCM). In this study, the polyethylene glycol/silicon dioxide composites as form-stable, solid–liquid phase change material (PCM) was prepared. In this new material, the polyethylene glycol acts as the latent heat storage material and silicon dioxide serves as the supporting material, which provides structural strength and prevents the leakage of the melted polyethylene glycol. Results indicated that the composite remained solid when the weight percentage of silicon dioxide was higher than 15%. Moreover, the polyethylene glycol was observed to disperse into the network of the solid silicon dioxide by investigation of the structure of the composite PCMs using a scanning electronic microscope (SEM). The properties of the porous materials and phase change materials were characterized using Fourier transformation infrared spectroscope (FTIR). The transition process was observed using polarizing optical microscope (POM) and dynamic thermo mechanic analysis (DMA). The melting temperatures and latent heats of the form-stable PEG/SiO2 composite PCMs were determined using differential scanning calorimeter (DSC).

sted, utgiver, år, opplag, sider
Elsevier, 2009
Emneord
Polyethylene glycol; Silicon dioxide; Heat storage materials; Phase change materials
HSV kategori
Forskningsprogram
energi- och miljöteknik
Identifikatorer
urn:nbn:se:mdh:diva-7452 (URN)10.1016/j.apenergy.2007.12.003 (DOI)000260269000007 ()2-s2.0-52149121582 (Scopus ID)
Tilgjengelig fra: 2009-11-16 Laget: 2009-10-30 Sist oppdatert: 2017-12-12bibliografisk kontrollert
2. Combined heat and power plant integrated with mobilized thermal energy storage (M-TES) system
Åpne denne publikasjonen i ny fane eller vindu >>Combined heat and power plant integrated with mobilized thermal energy storage (M-TES) system
Vise andre…
2010 (engelsk)Inngår i: Frontiers of Energy and Power Engineering in China, ISSN 1673-7393, Vol. 4, nr 4, s. 469-474Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Energy consumption for space heating and hot tap water in residential and service sectors accounts for one third of total energy utilization in Sweden. District heating (DH) has been used for heat supply to areas with high energy demand. However, there are still a lot of detached houses and sparse areas with no connection to a DH network where electrical heating or oil/pellet boilers are used to meet heat demand. Sometimes, extending the existing DH network to those spare areas is not economically feasible because of the small heat demands and the large investment. Mobilized thermal energy storage (M-TES) system is an alternative way to supply heat for detached buildings or sparse areas by using industrial heat. In this paper, integration of a combined heat and power (CHP) plant and an M-TES system is analyzed. The impacts of four options of the integrated system are discussed including the power and heat output in the CHP plant, as well as the performance of M-TES system.

sted, utgiver, år, opplag, sider
Springer, 2010
Emneord
Mobilized thermal energy system; District heating; Thermal energy storage; Combined heat and power; Detached houses
Forskningsprogram
energi- och miljöteknik
Identifikatorer
urn:nbn:se:mdh:diva-10638 (URN)10.1007/s11708-010-0123-9 (DOI)2-s2.0-78649903139 (Scopus ID)
Prosjekter
Ångpanneföreningens Forskningsstiftelse (ÅF), Sweden
Tilgjengelig fra: 2010-10-28 Laget: 2010-10-28 Sist oppdatert: 2013-12-04bibliografisk kontrollert
3. Enhanced thermal conductivity and thermal performance of form-stable composite phase change materials by using β-Aluminum nitride
Åpne denne publikasjonen i ny fane eller vindu >>Enhanced thermal conductivity and thermal performance of form-stable composite phase change materials by using β-Aluminum nitride
2009 (engelsk)Inngår i: Applied Energy, ISSN 0306-2619, E-ISSN 1872-9118, Vol. 86, nr 7-8, s. 1196-1200Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

β-Aluminum nitride powder is a promising additive due to its great conductivity value, which can enhance the thermal conductivity of organic phase change materials. In this paper, a high conductivity form-stable phase change material was prepared by blending polyethylene glycol, silica gel, and β-Aluminum nitride powder. The conductivity value of the composite PCMs was determined using the Hotdisk thermal analyzer, which is based on the transient plane source technique. Experiment of heat storage and release performance was carried out to investigate heat efficiencies of TES system. The results showed that thermal conductivity of composite PCMs increased with an increase in β-Aluminum nitride content, but the value of latent heat decreased correspondingly. There was no change on the melting temperature while different ratios of composites. The value of thermal conductivity changed from 0.3847 W m−1 K−1 to 0.7661 W m−1 K−1 with the increase of mass ratio of β-Aluminum nitride from 5% to 30%. The heat storage and release rate of the composite PCMs was higher than that of pure polyethylene glycol.

sted, utgiver, år, opplag, sider
Elsevier, 2009
Emneord
Polyethylene glycol; Silica gel; β-Aluminum nitride; Thermal conductivity
Forskningsprogram
energi- och miljöteknik
Identifikatorer
urn:nbn:se:mdh:diva-7453 (URN)10.1016/j.apenergy.2008.10.020 (DOI)000265033400025 ()2-s2.0-61849180914 (Scopus ID)
Tilgjengelig fra: 2009-11-16 Laget: 2009-10-30 Sist oppdatert: 2017-12-12bibliografisk kontrollert
4. Thermal performance of the mobilized thermal energy storage system
Åpne denne publikasjonen i ny fane eller vindu >>Thermal performance of the mobilized thermal energy storage system
2011 (engelsk)Konferansepaper, Publicerat paper (Fagfellevurdert)
Abstract [en]

A direct-contact mobilized thermal energy storage (M-TES) system with high heat density and heat transfer rate has been exploited to transport industrial heat for distributed users. In this paper, a lab-scale experimental setup has been built consisting of a direct-contact thermal energy storage (TES) container, oil/water tank, electrical boiler, oil/water pump and plate heat exchanger. Erythritol was chosen to work as an organic phase change material (PCM) due to its large heat density, suitable melting point (118oC) for industrial heat recovery, and non toxic and corrosive. Heat transfer oil (HTO) served as a heat transfer medium to carry and transfer heat. The theoretical heat capacity of the TES container is 13.1 kWh with 74 kg of Erythritol and 42 kg of HTO. In the charging process, electrical boiler heated HTO first, and then HTO was pumped into the bottom of the TES container to melt Erythritol directly. In the discharging process, heat was transferred to the cooling water through a plate heat exchanger. Results show that, the sub-cooling problem of Erythritol, which was found in the static experiments, was totally solved by dynamic heat exchange between Erythritol and HTO. During the whole process, the two liquid phases (oil and melted Erythritol) were separated clearly due to the big difference of their densities, and meanwhile a foam layer was also observed between the two sectors. In the charging process, the higher the flow rate of HTO, the less the charging time was needed, which resulted in the lower charging heat consumption. In the discharging process, the maximum heat of 10.6 kWh was released with the HTO flow rate of 12.5 l/min, which accounted for 80.9 % of the theoretical heat capacity of the TES container.

Emneord
Mobilized thermal energy storage system; Heat recovery; Phase change materials; distributed heating
HSV kategori
Identifikatorer
urn:nbn:se:mdh:diva-10640 (URN)
Konferanse
International Conference on Applied Energy, MAY 16-18, 2011 PERUGIA, ITALY
Prosjekter
Ångpanneföreningens Forskningsstiftelse (ÅF), Sweden
Tilgjengelig fra: 2010-10-28 Laget: 2010-10-28 Sist oppdatert: 2016-01-11bibliografisk kontrollert
5. Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage
Åpne denne publikasjonen i ny fane eller vindu >>Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage
2009 (engelsk)Inngår i: Applied Energy, ISSN 0306-2619, E-ISSN 1872-9118, Vol. 86, nr 9, s. 1479-1483Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Expanded graphite is a promising heat transfer promoter due to its high conductivity, which improves the thermal conductivity of organic phase change materials. Moreover, it can also serve as supporting materials to keep the shape of the blends stable during the phase transition. After various investigation, the results showed that the maximum weight percentage of polyethylene glycol was as high as 90% in this paper without any leakage during the melting period, with the latent heat of 161.2 J g−1 and the melting point of 61.46 °C. It was found that the value of the latent heat was related to the polyethylene glycol portion, increased with the increase in polyethylene glycol content. Moreover, the measured enthalpy of the composite phase change materials was proportional to the mass ratio of the polyethylene glycol component. The melting temperatures were almost the same with different ratios of composites. The conductivity of blends was improved significantly with the high value of 1.324 W m−1 K−1 compared to the pure polyethylene glycol conductivity of 0.2985 W m−1 K−1.

sted, utgiver, år, opplag, sider
Elsevier, 2009
Emneord
Polyethylene glycol; Expanded graphite; Form-stable materials; Thermal conductivity
HSV kategori
Forskningsprogram
energi- och miljöteknik
Identifikatorer
urn:nbn:se:mdh:diva-7451 (URN)10.1016/j.apenergy.2008.12.004 (DOI)000265735300015 ()2-s2.0-63449093377 (Scopus ID)
Tilgjengelig fra: 2009-11-16 Laget: 2009-10-30 Sist oppdatert: 2017-12-12bibliografisk kontrollert
6. A new mobilized energy storage system for industrial waste heat recovery for distributed heat supply
Åpne denne publikasjonen i ny fane eller vindu >>A new mobilized energy storage system for industrial waste heat recovery for distributed heat supply
2009 (engelsk)Konferansepaper, Publicerat paper (Fagfellevurdert)
Abstract [en]

This paper introduces a new mobilized thermal energy storage (M-TES) for the recovery ofindustrial waste heat for distributed heat supply to the distributed users which have not beenconnected to the district heating network. In the M-TES system, phase-change materials (PCM)are used as the energy storage and carrier to transport the waste heat from the industrial site to theend users by a lorry. A technical feasibility and economic viability of M-TES has been conductedwith the comparison of the district heating system as a reference. Thermal performance and costimpacts by different PCM materials have been analyzed compared, aiming at determining theoptimum operation conditions. A case study is investigated by utilizing the waste heat from acombine heat and power (CHP) plant for the distributed users which are located at over 30kilometers away from the plant. The results show that the M-TES may offer a competitivesolution compared to building or extending the existing district heating network.

Emneord
Mobile energy storage system; Energy storage materials; Industrial waste heat;
HSV kategori
Forskningsprogram
energi- och miljöteknik
Identifikatorer
urn:nbn:se:mdh:diva-7600 (URN)
Konferanse
The First International Conference on Applied Energy (ICAE’09), Hong Kong, January 5-7, 2009
Tilgjengelig fra: 2009-11-29 Laget: 2009-11-29 Sist oppdatert: 2016-01-12bibliografisk kontrollert

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